期刊
CRYSTAL GROWTH & DESIGN
卷 17, 期 5, 页码 2822-2827出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.7b00278
关键词
-
资金
- Research Grants Council of Hong Kong [14303816]
Hydrogen-bond-assisted host guest complexation of a tris(catechol)-functionalized tribenzotriquinacene with various tetraalkylammonium halides yielded diversified supramolecular architectures ranging from octameric C-3-symmetric cages and C-2- and C-4-symmetric channels to corrugated layers, depending on both the anionic and cationic components of the guest species. Single crystal X-ray analyses of this series of complexes revealed intricate anionic host networks formed by intermolecular O-H center dot center dot center dot O and O-H center dot center dot center dot X hydrogen-bonds involving catechol host molecules and halides, which accommodate the bulky quaternary ammonium guest ions in cavities, channels, or between corrugated sheets. With fine-tuning of the symmetry and size of the hydrophobic cationic guest and accompanying halide species, this simple Mix and Match of host and guest components provides an efficient route to the assembly of supramolecular architectures.
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