期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 23, 页码 6435-6439出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201700282
关键词
alkynes; gold; heterogeneous catalysis; hydrochlorination; vinyl chlorides
资金
- ITQ
- Severo Ochoa program
HCl in solution accepts electron density from Au NPs and partially reduces at room temperature, as occurs with other simple diatomic molecules, such as O-2 and H-2. The activation can be run catalytically in the presence of alkynes to give exclusively E-vinyl chlorides, after the regio-and stereoselective transfer of HCl. Based also on this method, vinyl chloride monomer (VCM) can be produced in a milder and greener way than current industrial processes.
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