期刊
C-JOURNAL OF CARBON RESEARCH
卷 3, 期 2, 页码 -出版社
MDPI
DOI: 10.3390/c3020017
关键词
chromium; tungsten; carbon nanotube; graphene; XPS
资金
- Office of Naval Research [N00014-15-2717]
- Welsh Government Ser Cymru National Research Network in Advanced Engineering and Materials [NRN-150]
- Robert A. Welch Foundation [C-0002]
- Lockheed Martin Corporation
The reaction of Group 6 metals with SWCNT has the potential to bridge the resistive SWCNT ... SWCNT junctions by the formation of Cr(SWCNT)(2) complexes analogous to Cr(C6H6)(2). This study reports that the formation of such species is very sensitive to oxidation by a residual iron oxide catalyst used for the growth of the SWCNTs and adsorbed/bound oxygen functionality. The reaction of raw HiPco SWCNTs with M(CO)(6) and (C7H8)M(CO)(3) (M = Cr, W) or (C6H6)Cr(CO)(3) results in the formation of the Group 6 metal oxides. Annealing and acid treating the HiPco SWCNTs to reduce the catalyst content allows for the observation of zero valent metals by XPS, while the use of very high purity SWCNTs and graphene allows for the addition of primarily zero valent Group 6 metals, including the bis-hexahapto metal complex.
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