期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 23, 页码 6511-6514出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201702063
关键词
macrocycles; meta-phenylene; molecular recognition; nanostructures; self-assembly
资金
- JST ERATO [JPMJER1301]
- KAKENHI [24241036, 25102007, 16K04864]
- Grants-in-Aid for Scientific Research [17H01033, 16K04864, 25102007] Funding Source: KAKEN
A phenylene multiring with a corannulenoidal skeleton was synthesized. Geodesic constraints over 20 phenylene panels resulted in its nanometer-sized, bowl-shaped molecular structure, which was unequivocally revealed by crystallographic analysis. The crystal structure also showed the presence of a bowl-in-bowl dimeric assembly, which was driven by entropic factors in solution.
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