期刊
RSC ADVANCES
卷 7, 期 65, 页码 40881-40886出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra07209k
关键词
-
资金
- Science and Research Branch, Islamic Azad University
In this paper we report an efficient method for the aerobic oxidation of benzyl alcohols to aldehydes by supported palladium nanoparticles in a nanoporous metal-organic framework Cu-2(BDC)(2)(DABCO) (BDC = 1,4benzenedicarboxylate, DABCO = 1,4-diazabicyclo[2.2.2] octane) under a temperature control program and through reduction by dimethylformamide. The Pd-NPs/Cu-2(BDC)(2)(DABCO) offered higher catalytic activity and recyclability than reported in literature. The supported Pd nanoparticles (PdNPs/Cu-2(BDC)(2)(DABCO)) were characterized by X-ray diffraction, BET analysis, field emission scanning electron microscopy, transmission electron microscopy, inductively coupled plasma atomic emission spectroscopy and X-ray photoelectron spectroscopy (XPS).
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