期刊
RSC ADVANCES
卷 7, 期 38, 页码 23293-23300出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra02126g
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资金
- Research Council of Azarbaijan Shahid Madani University [ASMU/95372-16]
In this study, silica-coated magnetite nanoparticles modified with triethoxysilylpropylpyridinium hexafluorophosphate ionic liquid were synthesized and used as a sorbent for the solid-phase extraction and preconcentration of zinc ions from aqueous solutions. The structure and morphology of the synthesized nanosorbent were characterized by X-ray diffraction, scanning electron microscopy, and Fourier transform infrared spectroscopy. After desorption with acidic ethanol, zinc was quantified by flame atomic absorption spectrometry. The experimental factors affecting the extraction/preconcentration of the analyte were investigated and optimized. Under the optimized experimental conditions, the calibration graph was linear in the concentration range of 0.5-15 ng mL(-1) (with an R-2 value of 0.998). The limit of detection and the preconcentration factor were 0.17 ng mL(-1) and 100, respectively. The relative standard deviation for six replicate determinations of 10 ng mL(-1) Zn was 2.3%. The method was validated by the successful analysis of a standard reference material (NIST SRM 1549; non-fat milk powder) and employed for the determination of zinc in several samples of water and milk, with recoveries in the range of 97.0-102.5% for the spiked samples.
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