Preparation of electrolyzed oxidizing water with a platinum electrode prepared by magnetron sputtering technique

Electrolyzed oxidizing water (EO water) with low pH (2.2-2.7), high oxidation-reduction potential (ORP > 1100 mV), and available chlorine content (ACC) of 30-80 mg L-1 has an efficiently bactericidal activity and wide adaptability against many food-borne pathogens. EO water could be generated by electrolysis of a dilute NaCl solution in an electrolysis chamber with a Pt/Ti electrode. In this study, the Pt/Ti electrode was prepared by magnetron sputtering technique. The electrode surface has the characteristic of specific growth along the [111] direction. At the same time, the platinum electrodes prepared through thermal decomposition and electrodeposition as the control were also investigated. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were employed to study the performances of these three types of Pt/Ti electrode. The effects of the physicochemical properties of the Pt electrodes on their electrochemical behaviors were studied. Furthermore, the values of pH, ORP, ACC, Cl- and the sterilization effect of EO water using these Pt electrodes as anode materials have been systematically discussed. In addition, the content of HClO, ClO-, O-3 and dissolved oxygen in EO water using the Pt-MS electrode has also been reported in this article.