4.6 Article

The electrochemical behavior of an aluminum alloy anode for rechargeable Al-ion batteries using an AlCl3-urea liquid electrolyte

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RSC ADVANCES
卷 7, 期 51, 页码 32288-32293

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra05860h

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  1. Fundamental Research Funds for the Central Universities [FRF-TP-15-002C1]

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Due to its characteristics of high capacity, low cost, being non-flammable, and involving a three-electron-redox reaction, the aluminum rechargeable battery has received wide attention. Because of these advantages, we focus on a low-cost aluminum alloy anode and detect the discharge/charge reaction mechanism in the aluminum chloride-urea liquid electrolyte at 110-130 C-omicron. The discharge voltage of the battery is about 1.9 V and 1.6 V, and at the current density of 100 mA g(-1) the cell can produce a specific capacity of similar to 94 mA h g(-1). Compared to the pure aluminum anode, the system has a promising future for high efficiency, low-cost energy storage devices.

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