期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 43, 页码 5906-5909出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc03107f
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资金
- Alexander von Humboldt-foundation
- CSC
- European Research Council under the Seventh Framework Program of the European Community (FP7) [307535]
Inexpensive copper catalysts enabled direct C-H chalcogenations at ambient temperature by means of photo-induced catalysis. The expedient copper catalysis set the stage for C-S and C-Se bond formation from readily accessible non-volatile elemental chalcogens. The photo-assisted copper catalysis manifold proved suitable for a wide range of substrates with good functional group tolerance and exhibited high catalytic efficacy even at a reaction temperature of 25 degrees C.
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