期刊
RSC ADVANCES
卷 7, 期 4, 页码 2273-2280出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra25714c
关键词
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资金
- National Natural Science Foundation of China [51471152, 51571178]
- National Materials Genome Project [2016YFB0700600]
- National Youth Top-Notch Talent Support Program
We demonstrate a first attempt to understand the particle size-dependence of electrochemical Li storage properties of silicon monoxide (SiO). SiO powder particles of different sizes are obtained by planetary ball milling at 300 rpm for 0-12 h. The 10 h-milled SiO sample exhibits relatively uniform particle morphology with significantly reduced particle size, which induces optimal electrochemical Li storage properties. The specific surface area of the 10 h-milled SiO sample is determined to be approximately 20.1 m(2) g(-1), which is more than 22 times that of pristine SiO (similar to 0.9 m(2) g(-1)). The first discharge and charge capacities of the 10 h-milled SiO sample are 2684 and 2091 mA h g(-1), respectively, at 100 mA g(-1). After 150 cycles, the discharge capacity of the 10 h-milled sample remains at 1159 mA h g(-1), while the discharge capacity is only 777 mA h g(-1) for the pristine SiO sample. The mechanism of the capacity loss upon cycling is also analysed and discussed.
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