期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 33, 页码 7900-7904出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201701665
关键词
aryl radical; C-C bond formation; lanthanides; photoredox catalysis; photoreduction
资金
- German Science Foundation (DFG) [GRK 1626]
- Fonds der Chemischen Industrie
- Experientia Foundation
Metal ions can have beneficial effects on photoinduced electron transfer. Merging such metal-ion-coupled electron transfer (MCET) with consecutive photoinduced electron transfer (conPET) enables the one-electron reduction of chlorobenzene with blue light in the presence of diisopropylethylamine as an electron donor. The presence of the metal ions extends the substrate scope of the photoredox catalysis to extreme reduction potentials (beyond - 3 V vs. SCE).
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