期刊
RSC ADVANCES
卷 7, 期 14, 页码 8542-8549出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra27709h
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资金
- National Natural Science Foundation of China [51262027]
- Natural Science Foundation of Gansu Province [0803RJZA009]
- Science and Technology Tackle Key Problem Item of Gansu Province [2GS064-A52-036-08]
- Gansu Key Laboratory of Polymer Materials [ZD-04-14]
- State Key Laboratory of Solidification Processing in NWPU [SKLSP201011]
A simple chiral electrochemical sensor based on hydroxypropyl chitosan (HPCS) covalently bound to multi-walled carbon nanotubes (MWCNTs) was developed for the recognition of mandelic acid (MA) enantiomers. HPCS preferably combines with (S)-MA over (R)-MA, which was attributed to the favorable host-guest interactions between HPCS and the MA enantiomers. In addition, the recognition efficiency was significantly increased after hydroxypropyl groups were grafted onto chitosan (CS), which may be due to a stereo-hindrance effect. Moreover, the electrochemical recognition of amino acid enantiomers was investigated; the functional groups of the enantiomers play an important role in the enantioselective discrimination.
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