期刊
RSC ADVANCES
卷 7, 期 62, 页码 38884-38894出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra05167k
关键词
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资金
- National Natural Science Foundation of China [31571798, 31401618, 31000831]
- Natural Science Foundation of Heilongjiang Province [C2016033]
- National Science Foundation for Postdoctoral Scientists of China [2014M551260]
- Natural Science Research and Innovation Funds of Harbin Institute of Technology [HIT.NSRIF.2014093]
- Harbin Young talent reserve project [2014RFYJ179]
- Youth Science Fund Project of Heilongjiang Province [QC2013C026]
In this study, we report a facile method for the preparation of molecularly imprinted polymer based graphene for the electrochemical detection of thiamethoxam residue. We choose p-vinylbenzoic acid as a functional monomer; it can be used to add recognition units and alkenyl units onto the surface of graphene via pi-pi interactions in just one step, effectively simplifying the reaction process. And an ultrathin imprinting film (2 nm) is formed by reducing the addition step involving the alkenyl modifier. Due to the irreversible electrochemical reduction characteristics of thiamethoxam, the template can be removed easily using cyclic voltammetry scanning, without the need for organic solvents. The performance of the fabricated sensor was evaluated and the results indicated that the sensor exhibited excellent specific recognition abilities for thiamethoxam detection; the imprinting factor is 2.36. The peak current from thiamethoxam is linearly proportional to its concentration over the range from 0.5 to 20 mu M, and the detection limit is 0.04 mu M. The practical application of the sensor was also realized in the selective detection of thiamethoxam in real samples.
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