Tunable emission of single-phased NaY(WO4)2:Sm3+ phosphor based on energy transfer

A series of NaY(WO4)(2):Sm3+ phosphors were prepared by high temperature solid state reaction. When excited by ultraviolet and blue light, their emission spectra cover entirely visible light region, due to intrinsic luminescence of WO42- group as well as Sm3+ 4f-4f transitions. White light emission was obtained from NaY0.99Sm0.01(WO4)(2) phosphor under radiation of 265 nm UV light, and intense yellow and red emission from H-6(J(J=5/2,7/2,9/2)) transitions were observed when pumped Sm(3+4)G(5/2) by 405 nm blue light. With incorporation of Sm3+ into NaY(WO4)(2) host, higher-level emission from Sm3+ at 650 nm was generated by energy transfer from WO42- to Sm3+ under excitation of 265 nm. The corresponding energy transfer mechanism was demonstrated to be a dipole-dipole interaction. In addition, tunable emission from blue to white and, finally, to red was realized by increasing Sm3+ doping concentration. The band gap of NaY(WO4)(2) calculated from diffuse reflection spectra indicates a semiconducting character. All these results show that NaY1-lambda Smx(WO4)(2) phosphor provides promising application for conversion of frequencies emitted by UV or blue LEDs.