4.7 Article

Molecular tectonics: gas adsorption and chiral uptake of (L)- and (D)-tryptophan by homochiral porous coordination polymers

期刊

CHEMICAL COMMUNICATIONS
卷 53, 期 42, 页码 5740-5743

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc01554b

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资金

  1. Universite de Strasbourg
  2. C.N.R.S.
  3. International centre for Frontier Research in Chemistry (icFRC)
  4. Labex CSC within the Investissement d'Avenir program [ANR-10-LABX-0026 CSC, ANR-10-IDEX-0002-02]
  5. Institut Universitaire de France
  6. Ministere de l'Enseignement Superieur et de la Recherche
  7. PRIN [2016-CTEBBA]
  8. INSTM/Lombardy Region
  9. Cariplo Foundation

向作者/读者索取更多资源

Combinations of two enantiomerically pure organic tectons 1 and 3 with either Zn(II) or Cu(II) cations lead to the formation of four homochiral 3D networks among which two, 1-Cu and 3-Cu, are robust porous crystals displaying homochiral cavities and permanent microporosity. 3-Cu porous crystals capture 66% and 20% of L-and D-tryptophan, respectively, after 30 min of adsorption.

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