期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 32, 页码 7825-7829出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201701535
关键词
C-H activation; cycloaddition; dehydrogenative coupling; metal-free synthesis; oxidative coupling
资金
- Max-Planck Gesell-schaft
- Ministry of Education and Science of the Russian Federation [02.a03.21.0008]
Functionalization of C(sp(3))-H bonds under metal-free reaction conditions is a great challenge due to poor bond reactivity. A novel metal-free oxidative dehydrogenative Diels-Alder reaction of alkylbenzene derivatives with alkenes through C(sp(3))-H bond functionalization is described. The developed oxidative method provides a straightforward approach to biologically relevant 1,4-phenanthraquinone and isoindole derivatives from readily available starting materials. Furthermore, the synthesis of nitrostyrenes from enylbenzene derivatives by selective C(sp(3))-H bond functionalization has been demonstrated.
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