期刊
RSC ADVANCES
卷 7, 期 36, 页码 22353-22359出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra00296c
关键词
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资金
- Beijing Natural Science Foundation [2172037]
- National Natural Science Foundation of China [51503016]
- State Key Laboratory of Chemical Resource Engineering
- Fundamental Research Funds for the Central Universities [FRF-TP-16-004A3]
An efficient Cu(I)-catalyzed aerobic alcohol oxidation system was developed utilizing a novel metal-organic framework (MOF) ligand at room temperature. Several relatively inert secondary alcohols were converted to their corresponding ketones in high yields and selectivities in the presence of a Cu(I) catalyst and air as the oxidant. This newly developed Cu(I)/MOF ligand system can also be easily extended to the aerobic oxidation of primary alcohols including aliphatic ones. Furthermore, the MIL-101-N-2-pyc ligand can be recycled several times without compromising reaction activity.
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