期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 26, 页码 7531-7534出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201701365
关键词
alcohols; esters; homogeneous catalysis; hydrogenation; manganese
资金
- Ministry of Education, Culture and Science of the Netherlands
- Government of the Russian Federation through the ITMO Fellowship and Professorship Program [074-U01]
- NWO
Catalytic hydrogenation of carboxylic acid esters is essential for the green production of pharmaceuticals, fragrances, and fine chemicals. Herein, we report the efficient hydrogenation of esters with manganese catalysts based on simple bidentate aminophosphine ligands. Monoligated Mn PN complexes are particularly active for the conversion of esters into the corresponding alcohols at Mn concentrations as low as 0.2 mol% in the presence of sub-stoichiometric amounts of (KOBu)-Bu-t base.
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