期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 11, 页码 1825-1830出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700241
关键词
azines; diazo compounds; fluorescence; N-heterocyclic carbenes; N-tosylhydrazones
资金
- National Natural Science Foundation of China [21302081]
- Scientific Fund of Sichuan Province, China [2014JQ0052]
- Education Department of Sichuan Province [13ZA0232]
- Science and Technology Project of Luzhou City [2013LZLY-K72]
An efficient synthesis of azines from the reaction of N-heterocyclic carbene precursors with N-tosylhydrazones has been developed. This method avoids the direct use of diazo compounds and allows the synthesis of structurally diverse azines. An azine was further found to exhibit strong yellow fluorescence and shows promise as a reagent for biological imaging.
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