期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 30, 页码 7221-7226出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201701410
关键词
fenton; hydroxyl radicals; programmable polymer synthesis; adical polymerization; RAFT
资金
- Melbourne International Research Scholarship (MIRS)
- Melbourne International Fee Remission Scholarship (MIFRS)
- [FT110100411]
- Australian Research Council [FT110100411] Funding Source: Australian Research Council
Fine control over the architecture and/or microstructure of synthetic polymers is fast becoming a reality owing to the development of efficient and versatile polymerization techniques and conjugation reactions. However, the transition of these syntheses to automated, programmable, and high-throughput operating systems is a challenging step needed to translate the vast potential of precision polymers into machine-programmable polymers for biological and functional applications. Chain-growth polymerizations are particularly appealing for their ability to form structurally and chemically well-defined macromolecules through living/controlled polymerization techniques. Even using the latest polymerization technologies, the macromolecular engineering of complex functional materials often requires multi-step syntheses and purification of intermediates, and results in sub-optimal yields. To develop a proof-of-concept of a framework polymerization technique that is readily amenable to automation requires several key characteristics. In this study, a new approach is described that is believed to meet these requirements, thus opening avenues toward automated polymer synthesis.
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