期刊
COORDINATION CHEMISTRY REVIEWS
卷 344, 期 -, 页码 345-354出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2016.12.008
关键词
Bridged systems; Noninnocent ligands; Oxidation states; Radical ligands; Redox reactions
资金
- Deutsche Forschungsgemeinschaft
- EU [COST CM1202]
- Fonds der Chemischen Industrie
Three-center bridged situations Ru-L-Ru and Q-M-Q (M = Ru, Co, Ni, Cu) containing redox-active transition metals and noninnocently behaving ligand redox systems L-k or Q(n) (o-iminoquinone/o-iminosemiquinone/o-amidophenolate series) can provide valuable insight into electronic and spin interactions of correlated coordination compounds. Experimental approaches using combined structural, electrochemical, spectroscopic (UV-vis-NIR) and magnetic resonance methods were employed with computational support to elucidate which of the potential alternatives are most appropriate to describe the individual electronic structures. (C) 2016 Elsevier B.V. All rights reserved.
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