4.7 Article

A cuboidal [Ni4O4] cluster as a precursor for recyclable, carbon-supported nickel nanoparticle reduction catalysts

期刊

DALTON TRANSACTIONS
卷 46, 期 22, 页码 7154-7158

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt01579h

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资金

  1. National Natural Science Foundation of China [21401134, 21531006, 21671143]
  2. State Key Laboratory of Organometallic Chemistry of the Shanghai Institute of Organic Chemistry [2015kf-07]
  3. Science and Technology Department of Jiangsu Province [BK20140307]
  4. Department of Education of Jiangsu Province [14KJB150023]
  5. Jiangsu Higher Education Institutions

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Cuboidal [Ni4O4] clusters supported by a pyridine alkoxide ligand have been developed. One of these clusters was selected as a precursor for carbon-hosted Ni nanoparticles (NiNPs/C) which were efficient catalysts for the conversion of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) at room temperature.

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