期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 14, 页码 2469-2477出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201500142
关键词
Photophysics; Solar cells; Sensitizers; Dyes; Pigments; Charge transfer; Iron; Carbene ligands
资金
- Universite de Lorraine
- Centre National de la Recherche Scientifique (CNRS)
- IS2-SAS
- CNRS
Herein, we report a homoleptic iron complex bearing tridentate bis-carbene (CNC) ligands designed for sensitization of TiO2 photoanodes. Its excited state has been characterized by ultra-fast transient spectroscopy and time-dependent density functional theory (TD-DFT) computations, which reveal a record triplet metal-to-ligand charge-transfer ((MLCT)-M-3) excited-state lifetime (16 ps). The new dye was efficiently chemisorbed on TiO2 and promoted electron injection and photocurrent generation in a dye-sensitized solar cell upon solar irradiation.
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