期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 27, 页码 7826-7830出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201703334
关键词
density functional calculations; small ring systems; photocatalysis; reaction mechanisms; ring expansion
资金
- Spanish Government [CTQ2015-64561-R, CTQ2014-59544-P]
- European Research Council (ERC-CG) [647550]
- UAM
- MINECO
- ICREA
- European Research Council (ERC) [647550] Funding Source: European Research Council (ERC)
Described herein is a new visible-light photocatalytic strategy for the synthesis of enantioenriched dihydrofurans and cyclopentenes by an intramolecular nitro cyclopropane ring expansion reaction. Mechanistic studies and DFT calculations are used to elucidate the key factors in this new ring expansion reaction, and the need for the nitro group on the cyclopropane.
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