期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 18, 页码 3019-3027出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201500263
关键词
Lanthanides; Charge transfer; Energy transfer; Luminescence; Triboluminescence
资金
- Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq)
- Instituto Nacional de Ciencia e Tecnologia - Instituto Nacional de Nanotecnologia para Marcadores Integrados (INCT-INAMI)
- Programa de Apoio a Nucleos de Excelencia-Fundacao de Amparo a Ciencia e Tecnologia de Pernambuco (PRONEX-FACEPE)
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES)
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP)
Two new bis(dipivaloylmethanate)nitrato-bis(triphenylphosphine oxide)lanthanide(III) complexes [Eu(dpm)(2)(NO3)(tppo)(2)] (1) and [Tb(dpm)(2)(NO3)(tppo)(2)] have been prepared in monomeric form. The structural behavior of these coordination compounds is significantly different from those of [Eu-2(dpm)(6)] and [Tb-2(dpm)(6)] dimeric complexes. The photoluminescent properties of the monomeric and dimeric complexes are dependent on the energy positions of the low-lying ligand-to-metal charge-transfer (LMCT) state, which may be correlated with the chelating and chelate bridging coordination modes of the dpm ligand, respectively. The monomeric complex presents higher luminescence intensity than the dimeric complex due to the higher energy of the LMCT state in this system. Although the excited energy levels of the Eu-III ion in complex 1 undergo efficient depopulation by LMCT, the same is not observed for the D-5(0) emitting level, which presents values of the emitting lifetime that are almost temperature independent. The triboluminescence phenomenon of the [Ln(dpm)(2)(NO3)(tppo)(2)] complex is also discussed.
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