期刊
MATERIALS CHEMISTRY FRONTIERS
卷 1, 期 7, 页码 1331-1337出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6qm00377j
关键词
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资金
- National Natural Science Foundation of China [51072013, 51272021, 51142004, 51402010]
- Natural Science Foundation of Jiangsu Province [BK20131147, BK20140270]
Hollow-structured carbon nanofibers embedded with ultrafine SnOx nanoparticles (SnOx/H-CNFs) have been prepared by a simple single-spinneret electrospinning technique assisted by phase separation between polyvinylpyrrolidone and tetraethyl orthosilicate. The nitrogen adsorption-desorption isothermal analysis shows that the SnOx/H-CNFs possess a large specific surface area of 739 m(2) g(-1) and large amounts of mesopores. The high specific surface area provides a large electrode/electrolyte contact interface for Li+ transport and storage, while the hollow structure shortens the Li+-diffusion pathway and thus favors the rate capability. Moreover, the hollow and porous carbon matrix can act as a buffer zone to accommodate the volume change of the highly active SnOx during the lithiation/delithiation processes. Consequently, the SnOx/H-CNF electrode delivers a high reversible capacity of 732 mA h g(-1) at the rate of 500 mA g(-1) upon the 100th cycle, good rate performance (254 mA h g(-1) at 4 A g(-1)), and long-term cycling stability (513 mA h g(-1) at 1 A g(-1) after 500 cycles).
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