期刊
ACS NANO
卷 11, 期 7, 页码 7409-7415出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.7b03684
关键词
inverted structure; macromolecular additive; n-type conjugated polymer; polymer solar cells; thermal stability
类别
资金
- National Research Foundation of Korea (NRF) - Korea government (MSIP) [2015R1A2A1A10053397]
- Basic Science Research Program through National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [2015R1D1A1A0105791]
- National Research Foundation of Korea [2015R1A2A1A10053397] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Operational stability and high performance are the most critical issues that must be addressed in order to propel and advance the current polymer solar cell (PSC) technology to the next level, such as manufacturing and mass production. Herein, we report a high power conversion efficiency (PCE) of 11.2%, together with an excellent device stability in PTB7-Th:PC71BM-based PSCs in the inverted structure by introducing the n-type P(NDI2OD-T2) macromolecular additive (>75% PCE retention at high temperature up to 120 degrees C, >97% PCE retention after 6 months in inert conditions, >93% PCE retention after 2 months in air with encapsulation, and >80% PCE retention after 140 h in air without encapsulation). The PCE is the highest value ever reported in the single-junction systems based on the PTB7 family and is also comparable to the previously reported highest PCE of inverted PSCs. These promising results are attributed to the efficient optimization and stabilization of the blend film morphology in the photoactive layer, achieved using the P(NDI2OD-T2) additive. From the perspective of manufacturing, our studies demonstrate a promising pathway for fabricating low-cost PSCs with high efficiency as well as long-term stability.
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