期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 52, 页码 7076-7079出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc03544f
关键词
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资金
- EPSRC [EP/L023652/1, EP/K023004/1, EP/H024107/1, EP/I033459/1, EP/J015156/1]
- University of Glasgow
- ERC [670467]
- EPSRC [EP/H024107/1, EP/L023652/1, EP/K023004/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/L023652/1, EP/H024107/1, EP/K023004/1] Funding Source: researchfish
- European Research Council (ERC) [670467] Funding Source: European Research Council (ERC)
We report a {Cu-16} embedded within a {W-44} cluster containing four cubane- like [ Cu4O4] units within an isopolyoxotungstate (isoPOT) in a {Na4Cu4[(H2W11O38) (CH3COO)(OH)(3)]}(4)center dot 88H(2)O (1) and a polyanion Cu-linked {W-11} chain Na6Cu2[(H2W11O38)(CH3COO)(OH)] center dot 26H(2)O (2). Electronically, the redox properties show that both compounds 1 and 2 undergo irreversible reductions resulting in the demetalation of the compounds, whilst the magnetic behavior of 1 and 2 shows a weak antiferromagnetic and a stronger ferromagnetic coupling, respectively.
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