期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 12, 期 13, 页码 1480-1484出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201700456
关键词
density functional calculations; Diels-Alder; natural products; sorbicillins; total synthesis
资金
- Australian Research Council [DP150101947, CE140100012]
- CSC of the People's Republic of China
The enantiomer, ent-4, of the true structure, 4, of the sorbicillinoid rezishanone C (sorbivinetone) has been synthesized from a homochiral cis-1,2-dihydrocatechol that is itself generated through the whole-cell biotransformation of toluene. These studies together with dispersion-corrected DFT calculations support the proposal that rezishanone C is an artefact of the isolation process and arises through a Diels-Alder reaction between ethyl vinyl ether and sorbicillinol (3).
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