期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 27, 页码 7975-7979出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201703324
关键词
boron heterocycles; borylenes; density functional calculations; iminoboranes; nitrenes
资金
- Deutsche Forschungsgemeinschaft
- Germany-India DAAD-DST Personnel Exchange Programme
Although the metathesis of metal-boron double bonds with elemental chalcogenides is an established process, no similar reactivity has been observed with element-nitrogen bonds. Such a reaction would provide a new route to iminoborane compounds (RB equivalent to NR'), which have recently experienced renewed synthetic interest. Herein, we present the first observation of M=B/C=N metathesis reactions, which led to the isolation of a stable iminoborane in addition to further iminoborane cycloaddition products.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据