期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 23, 页码 20142-20149出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b05963
关键词
conducting polymers hydrogels; polyaniline; freeze-thaw cycles; flexible supercapacitors; supramolecular self-assembly
资金
- National Natural Science Foundation of China [21474094, 81401531]
- Natural Science Foundation of Anhui Province [1508085QH154]
We report that a postsynthesis physical process (freeze thaw cycles) can reform the microstructure of conductive polymer hydrogels from: clustered nanoparticles to interconnected nanosheets, leading to enhanced mechanical and electrochemical properties. The polyaniline poly(vinyl alcohol) hydrogel after five freeze thaw cycles (PPH-5) showed remarkable tensile strength (16.3 MPa), large elongation at break (407%), and high electrochemical capacitance (1053 F.g(-1)). The flexible supercapacitor based on PPH-5 provided a large capacitance (420 mF.cm(-2) and 210 F.g(-1)) and high energy density (18.7 W.h.kg(-1)), whose robustness was demonstrated by its 100% capacitance retention after 1000 galvanostatic charge discharge cycles or after 1000 mechanical folding cycles. The outstanding performance enables PPH-5 based supercapacitor as a promising power device for flexible electronics, which also demonstrates the merit of freeze thaw cycles for enhancing the performance of functional hydrogels.
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