期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 28, 页码 8201-8205出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201703127
关键词
arenes; boron; formylation; organocatalysis; synthetic methods
资金
- NSF [CHE-1565085]
- ACS-PRF [57164-ND1]
- National Science Foundation of China [21372073, 21572055]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1565085] Funding Source: National Science Foundation
Reported herein is a conceptually novel organocatalytic strategy for the formylation of boronic acids. New reactivity is engineered into the alpha-amino-acid-forming Petasis reaction occurring between aryl boronic acids, amines, and glyoxylic acids to prepare aldehydes. The operational simplicity of the process and its ability to generate structurally diverse and valued aryl, heteroaryl, and alpha,beta-unsaturated aldehydes containing a wide array of functional groups, demonstrates the practical utility of the new synthetic strategy.
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