期刊
ADVANCED FUNCTIONAL MATERIALS
卷 27, 期 26, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201700068
关键词
chemiresistive graphene sensors; exhaled breath analyzers; halitosis; kidney disorders; single-stranded (ss) DNA-functionalization
类别
资金
- KIST Institutional Program [2E27270]
- Global Top Project - Korean Ministry of Environment [GT-11-F-02-002-1]
- Nano-Material Technology Development Program [2012M3A7B4049804]
- Industrial Technology Innovation Program - Ministry of Trade, Industry, & Energy (MI, Korea [10054548]
- Institute for Information & Communications Technology Promotion (IITP) - Korea government (MSIP) [R0126-16-1050]
- Institute for Information & Communication Technology Planning & Evaluation (IITP), Republic of Korea [R0126-16-1050, 2015-0-00318-003] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- Korea Environmental Industry & Technology Institute (KEITI) [GT-11-F-02-002-1] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- Ministry of Science & ICT (MSIT), Republic of Korea [2E27260] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Council of Science & Technology (NST), Republic of Korea [C37100] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Highly sensitive and selective chemiresistive sensors based on graphene functionalized by metals and metal oxides have attracted considerable attention in the fields of environmental monitoring and medical assessment because of their ultrasensitive gas detecting performance and cost-effective fabrication. However, their operation, in terms of detection limit and reliability, is limited in traditional applications because of ambient humidity. Here, the enhanced sensitivity and selectivity of single-stranded DNA-functionalized graphene (ssDNA-FG) sensors to NH3 and H2S vapors at high humidity are demonstrated and their sensing mechanism is suggested. It is found that depositing a layer of ssDNA molecules leads to effective modulation of carrier density in graphene, as a negative-potential gating agent and the formation of an additional ion conduction path for proton hopping in the layer of hydronium ions (H3O+) at high humidity (>80%). Considering that selectively responsive chemical vapors are biomarkers associated with human diseases, the obtained results strongly suggest that ssDNA-FG sensors can be the key to developing a high-performance exhaled breath analyzer for diagnosing halitosis and kidney disorder.
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