期刊
CHINESE JOURNAL OF ORGANIC CHEMISTRY
卷 37, 期 5, 页码 1165-1172出版社
SCIENCE PRESS
DOI: 10.6023/cjoc201701043
关键词
transition-metal catalysis; cycloaddition; vinylaziridine; ynamides; nitrogen heterocycles
资金
- Shanghai Sailing Program [15YF1403600]
- National Natural Science Foundation of China [21602062, 21373088, 21425205]
The first rhodium-catalyzed stereospecific intermolecular [3+2] cycloaddition reaction of vinylaziridines with ynamides was realized. The salient features of the transformation include broad substrate scope, mild reaction condition, and simple operation. Moreover, the chirality of vinylaziridines can be completely transferred to the cycloadducts, representing an atom-economic and enantiospecific protocol for the construction of valuable 2-amino pyrroline derivatives.
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