期刊
CHEMISTRY LETTERS
卷 46, 期 8, 页码 1096-1098出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.170394
关键词
Coupling reaction; Benzocycloalkanol; Nickel catalyst
资金
- JSPS KAKENHI [JP16KT0057, JP25708018, JP15H05803, 2408, JP15H00943]
- Frontier Research Base for Global Young Researchers, Osaka University, on the Program of MEXT
- Grants-in-Aid for Scientific Research [16KT0057] Funding Source: KAKEN
Nickel(0)-catalyzed coupling reactions of 1,6-and 1,7-enals with triethylsilane have been utilized to synthesize six- and seven-membered silyl-protected benzocycloalkanols. When triethylborane was employed as the reducing reagent, tetralol derivatives were obtained. Results of deuterium-labeling experiments suggest the formation of oxanickelacycles as a key reaction intermediate.
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