期刊
CHEMICAL ENGINEERING JOURNAL
卷 320, 期 -, 页码 308-318出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2017.02.087
关键词
MIL-101; MIL-53; CPM-5; Volatile organic compound; NTP-catalyst; Indoor air
资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Concordia University
In this study, three different metal organic frameworks, MIL-101, MIL-53, and CPM-5, are used as dual functional adsorbent/catalysts in a non-thermal plasma (NTP)-catalytic reactor. The adsorption and oxidation evaluations of these MOFs for the removal of one (1) ppm toluene and isobutanol are performed at both dry (RH = 0%) and humid (RH = 30%) conditions. Results show that at dry air condition, MIL-101 possesses the highest adsorption capacity; however, at 30% RH, MIL-53 capacity surpasses MIL-101 and CPM-5. The results of NTP-catalytic oxidation reactions demonstrate a high removal efficiency of isobutanol (100%) and toluene (similar to 90%) for all three MOF5 at dry air condition. At 30% humidity, on the other hand, the catalysts removal performance decreases. During the NTP-oxidation reaction different organic compounds and ozone are detected as by-products. Finally, FTIR spectroscopy of fresh and regenerated catalysts (MIL-101, MIL-53 and CPM-5) does not show a significant structural change. (C) 2017 Published by Elsevier B.V.
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