期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 14, 页码 2390-2395出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201601407
关键词
Ketones; Decarboxylation; Aldehydic C-H bonds; Oxidative cyclization; Diacylation
资金
- Foundation Research Project of Jiangsu Province (Natural Science Found) [BK20141359]
- Fundamental Research Funds for the Central Universities [KYTZ201604]
- 333 High Level Talent Project of JiangSu Province
Silver nitrate-catalyzed cascade decarboxylation and oxidative cyclization of alpha-oxocarboxylic acids, alkenes, and aldehydes is demonstrated for the first time. With ammonium persulfate as the oxidant, the cascade reactions afford dihydroflavonoid derivatives as products in moderate to good yields, exhibiting a broad substrate tolerance. Control experiments indicated that the mechanism includes a radical pathway with aldehydes as the carbon radical acceptors.
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