期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 30, 页码 8677-8680出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201702429
关键词
allenyl compounds; asymmetric synthesis; Lewis acids; pincer complex
资金
- MEXT (Japan)
- Tokyo Ohka Foundation
- Grants-in-Aid for Scientific Research [16K05720, 16J05331] Funding Source: KAKEN
The first highly enantioselective reaction of allenylnitriles with imines has been developed. Excellent yields and enantioselectivities were observed for the reaction with various imines using chiral Phebim-Pd-II complexes. This process offers a simple and efficient synthetic route for various functionalized alpha-vinylidene-beta-aminonitriles and their derivatives.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据