期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 56, 页码 7937-7940出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc04283c
关键词
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资金
- Board of Research in Nuclear Science (BRNS), Mumbai [37(2)/14/12/2015/BRNS/10549]
- UGC
Reported herein is the gold-catalyzed alkynylation of terminal alkynes using ethynylbenziodoxolones (EBXs), where EBXs serve a dual role as oxidants as well as alkyne transfer agents to access unsymmetrical 1,3-diynes. Hence, the catalytic system requires no external oxidants and is compatible with a broad range of substrates, including those with polar functional groups such as NH, OHand B(OH)(2).
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