4.6 Article

Metallicity without quasi-particles in room-temperature strontium titanate

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NPJ QUANTUM MATERIALS
卷 2, 期 -, 页码 -

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NATURE PUBLISHING GROUP
DOI: 10.1038/s41535-017-0044-5

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  1. Ile de France regional grant
  2. Fonds ESPCI-Paris
  3. JEIP-College de France
  4. QuantEmX grant from ICAM
  5. Gordon and Betty Moore Foundation [GBMF5305]

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Cooling oxygen-deficient strontium titanate to liquid-helium temperature leads to a decrease in its electrical resistivity by several orders of magnitude. The temperature dependence of resistivity follows a rough T-3 behavior before becoming T-2 in the lowtemperature limit, as expected in a Fermi liquid. Here, we show that the roughly cubic resistivity above 100 K corresponds to a regime where the quasi-particle mean-free-path is shorter than the electron wave-length and the interatomic distance. These criteria define the Mott-Ioffe-Regel limit. Exceeding this limit is the hallmark of strange metallicity, which occurs in strontium titanate well below room temperature, in contrast to other perovskytes. We argue that the T-3-resistivity cannot be accounted for by electron-phonon scattering a la Bloch-Gruneisen and consider an alternative scheme based on Landauer transmission between individual dopants hosting large polarons. We find a scaling relationship between carrier mobility, the electric permittivity and the frequency of transverse optical soft mode in this temperature range. Providing an account of this observation emerges as a challenge to theory.

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