期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 31, 页码 9146-9150出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201705399
关键词
counter electrodes; dye-sensitized solar cells; F-doped tin oxide; interconnected nanosheets; ternary sulfides
资金
- National Natural Science Foundation of China [61504076, 21574076, U1510121]
- National Natural Science Foundation of Shanxi Province [2015021129, 2014011016-1]
- Graduate student education innovation project [2016SY004]
- Doctoral education innovation project in Shanxi Province [2017-7]
The ternary iron-group thiospinels of metal diindium sulfides (MIn2S4, M = Fe, Co, Ni) with a vertically aligned nanosheet array structure are fabricated through an in situ solvothermal method on F-doped tin oxide (FTO) substrates, which are employed as one type of platinum (Pt)-free counter electrodes (CEs) in structure-dependent dye-sensitized solar cells (DSSCs). A DSSC assembled with ternary CoIn2S4 CE achieves an photoelectric conversion efficiency (PCE) of 8.83%, outperforming than that of FeIn2S4 (7.18%) and NiIn2S4 (8.27%) CEs under full sunlight illumination (100 mWcm(-2), AM 1.5 G), which is also comparable with that of the Pt CE (8.19%). Putting aside that the interconnected nanosheet array provides fast electron transfer and electrolyte diffusion channels, the highest PCE of CoIn2S4 based DSSC results from its largest specific surface area (144.07 m(2)g(-1)), providing abundant active sites and the largest electron injection efficiency from CE to electrolyte.
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