期刊
ADVANCED MATERIALS
卷 29, 期 28, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201606454
关键词
cathodes; Li-Se batteries; Li-Te; batteries; Li-I-2 batteries; Li-Br-2 batteries
类别
资金
- National Natural Science Foundation of China [51302079, 51671003]
- National Basic Research Program of China [2016YFB0100201]
- Australian Research Council [DP160102627]
Recent advances and achievements in emerging Li-X (X = O-2, S, Se, Te, I-2, Br-2) batteries with promising cathode materials open up new opportunities for the development of high-performance lithium-ion battery alternatives. In this review, we focus on an overview of recent important progress in the design of advanced cathode materials and battery models for developing high-performance Li-X (X = O-2, S, Se, Te, I-2, Br-2) batteries. We start with a brief introduction to explain why Li-X batteries are important for future renewable energy devices. Then, we summarize the existing drawbacks, major progress and emerging challenges in the development of cathode materials for Li-O-2 (S) batteries. In terms of the emerging Li-X (Se, Te, I-2, Br-2) batteries, we systematically summarize their advantages/disadvantages and recent progress. Specifically, we review the electrochemical performance of Li-Se (Te) batteries using carbonate-/ether-based electrolytes, made with different electrode fabrication techniques, and of Li-I-2 (Br-2) batteries with various cell designs (e.g., dual electrolyte, all-organic electrolyte, with/without cathode-flow mode, and fuel cell/solar cell integration). Finally, the perspective on and challenges for the development of cathode materials for the promising Li-X (X = O-2, S, Se, Te, I-2, Br-2) batteries is presented.
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