期刊
ADVANCED MATERIALS
卷 29, 期 28, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201700707
关键词
2D metal-organic hybrid materials; active-salt-templating; dopamine-FeCl3-6H(2)O; heteroatom-doped carbon; oxygen-reduction reaction
类别
资金
- Cluster of Excellence Unifying Concepts in Catalysis (UniCat) - German Science Foundation (DFG)
- Berlin Graduate School of Natural Sciences and Engineering (BIG-NSE) - German Science Foundation (DFG)
- ERC 2D MATER
2D porous carbon nanomaterials have attracted tremendous attention in different disciplines especially for electrochemical catalysis. The significant advantage of such 2D materials is that nearly all their surfaces are exposed to the electrolyte and can take part in the electrochemical reaction. Here, a versatile active-salt-templating strategy to efficiently synthesize 2D porous carbon nanosheets from layered organic-inorganic hybrids is presented. The resulting heteroatom-doped carbon nanosheets (NFe/CNs) exhibit exceptional performance for the oxygen-reduction reaction and in Zn-air battery electrodes. The activity of the best catalyst within a series of NFe/CNs exceeds the performance of conventional carbon-supported Pt catalysts in terms of onset potential (0.930 vs 0.915 V of Pt/C), half-wave potential (0.859 vs 0.816 V of Pt/C), long-time stability, and methanol tolerance. Also, when applied as a cathode catalyst in a zinc-air battery the NFe/CNs presented here outperform commercial Pt/C catalysts.
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