期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 7, 期 5, 页码 1193-1202出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cy00029d
关键词
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资金
- National Natural Science Foundation of China [51672089]
- State Key Laboratory of Advanced Technology for Material Synthesis and Processing (Wuhan University of Technology) [2015-KF-7]
- [201508020098]
In an attempt to construct extremely robust photocatalytic H-2-evolution systems, the search for highly active and durable earth-abundant H-2-evolution co-catalysts remains a great challenge. Herein, composite photocatalysts of g-C3N4 nanosheets and a Pt-like WC co-catalyst was firstly synthesized via a one-step high-temperature calcination strategy. The visible-light-driven photocatalytic hydrogen production performance over g-C3N4 nanosheets loaded by the earth- abundant tungsten carbide, which act as an active noble-metal-free co-catalyst, was further investigated using TEOA as an electron donor. The results showed that the loading of the WC co-catalyst could significantly boost the photocatalytic performance of g-C3N4 nanosheets under visible-light irradiation. Moreover, it was demonstrated that g- C3N4 nanosheets loaded with 15 wt% WC co-catalyst could achieve the highest hydrogen production rate of 146.1 mu mol g(-1) h(-1), which is 1.1 and 56.1 times that of the g-C3N4-1 wt% Pt and g-C3N4 photocatalysts, respectively. The remarkably enhanced hydrogen evolution activities could be ascribed to the loading of abundant WC cocatalyst onto the g-C3N4 nanosheets, which effectively improves visible-light absorption, promotes the separation of charge carriers, and enhances the subsequent hydrogen evolution kinetics. This study paves a new way for the rational design and development of extremely robust photocatalysts loaded by earth-abundant metal carbides, which can act as noble-metal-free co-catalysts, for the enhancement of H-2 evolution activity.
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