期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 7, 期 23, 页码 5510-5514出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cy01757j
关键词
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资金
- National Natural Science Foundation of China [21473109, 21773145]
- Science and Technology Program of Shaanxi Province [2016KJXX-26]
- Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University [16QNGG008]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT_14R33]
- 111 project [B14041]
- EPSRC [EP/K039687/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K039687/1] Funding Source: researchfish
Terminal alkenes were selectively cleaved into ketones and aldehydes catalyzed by a binuclear copper catalyst bearing a simple salicylate ligand with O-2 as the oxidant. The reaction was carried out under an atmosphere of O-2 (balloon) with 0.5 mol% of catalyst and could be performed on a gram scale, providing a convenient and practical method for the cleavage of terminal alkenes into carbonyl compounds.
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