期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 7, 期 6, 页码 1351-1362出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cy02577c
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资金
- Spanish Ministry of Economy and Competitiveness [CTQ 2015-69153-CO2-1, CTQ2014-53292-R]
- Generalitat Valenciana [Prometeo 2013014]
MIL-101(Cr) having substituents at the terephthalate linker (X = H, NO2, SO3H, Cl, CH3 and NH2) promotes the aerobic oxidation of benzylamines to the corresponding N-benzylidene benzylamines at different rates. MIL-101(Cr)-NO2 was the most active catalyst, about 6-fold more active than the parent MIL-101(Cr). MIL101(Cr)- NO2 does not deactivate significantly upon five consecutive reuses, does not leach the metal to the solution and maintains its crystallinity. MIL-101(Cr)-NO2 is active for a wide range of benzylamines including para-substituted, heterocyclic benzylamines and di-and tribenzylamines.
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