4.6 Article

Iridium(III)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

期刊

CATALYSIS SCIENCE & TECHNOLOGY
卷 7, 期 4, 页码 5843-5846

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cy02013a

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资金

  1. Russian Ministry of Education and Science [14.W03.31.0014]
  2. Russian Foundation for Basic Research [16-33-60123 mol_a_dk]
  3. Saint Petersburg State University [12.50.1188.2014]
  4. University of Liverpool
  5. EPSRC [EP/K039687/1] Funding Source: UKRI
  6. Engineering and Physical Sciences Research Council [EP/K039687/1] Funding Source: researchfish

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Cyclometallated iridium(III) complexes with 2-phenylpyridine [Ir(ppy)(2)(CNR)Cl] (ppy = (2-phenylpyridinato-C-2, N), R = Xyl, Mes), [Ir(ppy)(2)(CNR)(2)](OTf) (R = Xyl, Mes), and fac-[Ir(ppy)(3)] catalyse the cross-linking of polysiloxanes exclusively at temperatures above 100 degrees C leading to luminescent rubbers.

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