期刊
CHEMISTRY LETTERS
卷 46, 期 8, 页码 1211-1213出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.170475
关键词
N-Heterocyclic carbene (NHC); Phosphine oxide; Phosphorylation
资金
- JSPS KAKENHI [JP25708018, JP15K17824, JP15H00943, JP15H05803]
- Frontier Research Base for Global Young Researchers, Osaka University, on the program of MEXT
- Grants-in-Aid for Scientific Research [16KT0057] Funding Source: KAKEN
The direct syntheses of imidic-phosphinic mixed anhydrides and phosphinates were accomplished via phosphorylation of isocyanates or aldehydes with N-phosphine oxide-substituted imidazolylidenes (PoxIms) that are equipped with both nucleophilic carbene and electrophilic phosphorus moieties. In addition, the catalytic cyclotrimerization of phenyl isocyanate took place by employing a PoxIm having bis-N-phosphine oxide groups. The results presented in the current study demonstrate that judiciously designed multifunctional carbenes represent a promising potential for the phosphorylation of heterocumulenes and carbonyl compounds.
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