期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 7, 期 11, 页码 2274-2282出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cy00236j
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资金
- Universidad de Buenos Aires
- CONICET
- DEY
- AEC
- MEC
Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I.I-3] and visible light. This methodology bypasses the use of metal(organo) catalysts where the complex [(TMEDA)I.I3] acts as a good electron donor/reductant radical initiating agent. Biologically relevant sulfides are easily substituted with R-F moieties employing a mild and environmentally benign radical strategy starting from readily available RFI.
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