期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 32, 页码 9492-9496出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201705672
关键词
bismuth oxyhalides; nonlinear optical materials; second harmonic generation; structure-activity relationships; theoretical calculations
资金
- National Natural Science Foundation of China [91622124, 91022036, 21601056]
- China 863 project [2015AA034203]
- Youth Innovation Promotion Association CAS [2017035]
A family of nonlinear optical materials that contain the halide, oxide, and oxyhalide polar units simultaneously in a single structure, namely ABi(2)(IO3)(2)F-5 (A=K (1), Rb (2), and Cs (3)), have been designed and synthesized. They crystallize in the same polar space group (P2(1)) with a two-dimensional double-layered framework constructed by [BiF5](2-) and [BiO2F4](5-) units connected to each other by four F atoms, in which two [IO3](-) groups are linked to [BiO2F4](5-) unit on the same side. A hanging Bi-F bond of [BiF5](2-) unit is located on the other side via ionic interaction with the layer-inserted alkali metal ions to form three-dimensional structure. The well-ordered alignments of these polar units lead to a very strong second-harmonic generation response of 12 (1), 9.5 (2), and 7.5 (3) times larger than that of potassium dihydrogen phosphate under 1064 nm laser radiation. All of them exhibited a wide energy bandgap over 3.75 eV, suggesting that they will have a high laser damage threshold.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据